C60: the first one-component gel?

نویسندگان

  • C Patrick Royall
  • Stephen R Williams
چکیده

Until now, gels have been formed of multicomponent soft matter systems, consisting of a solvent and one or more macromolecular or colloidal species. Here we show that, for sufficient quench rates, the Girifalco model of C(60) can form gels which we identify by their slow dynamics and long-lived network structure. These gels are stable at room temperature, at least on the simulation time scale up to 100 ns. At moderate temperatures around 1000 K, below the bulk glass transition temperature, C(60) exhibits crystallization and phase separation proceeds without the dynamical arrest associated with gelation, in contrast to many colloidal systems.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A π-gel scaffold for assembling fullerene to photoconducting supramolecular rods

Nonequilibrium self-assembly of molecules holds a huge prospect as a tool for obtaining new-generation materials for future applications. Crystallization of neutral molecules within a supramolecular gel matrix is one example in which two nonequilibrium processes occur orthogonal to each other. On the other hand, electronically interacting donor-acceptor two-component systems are expected to for...

متن کامل

Click Coupling Fullerene onto Thermoresponsive Water-Soluble Diblock Copolymer and Homopolymer Chains at Defined Positions

We report on the synthesis of well-defined thermoresponsive water-soluble diblock copolymer and homopolymers functionalized with controlled numbers of C60 moieties at predetermined positions via the combination of atom transfer radical polymerization (ATRP) and click chemistry. Azide-containing polymer precursors including monoazide-terminated and R,R-diazide-terminated poly(N-isopropylacrylami...

متن کامل

Theoretical study of the properties of adenine amino acid tetomers with C60

In this research at the Adenine tautomers and their fullerene derivatives were optimized. NBO calculations and NMR for the tautomers and their Fullerene derivatives were carried out at the B3lyp/6-31G*quantum chemistry level. The core and the valence electrons of atoms were compared. Other cases examined in this study, resonance energy, chemical potential (µ ),...

متن کامل

Synthesis of polyvinyl pyridine/C60 conjugates in supercritical carbon dioxide*

In the present investigation efforts have been made to synthesis polyvinyl pyridine (PvPy) /C60 conjugates through 2, 2-azobisisobutyronitrile (AIBN) initiated insitu polymerization of PvPy in scCO2.The process of synthesis was monitored under different reaction conditions ranging 1200-1800psi, 60-90 oC over 6 hours. The progress of polymerization was monitored rheoviscometrically. The concentr...

متن کامل

Investigating the resonance energy and charge transfer in the clonidine and c60-clonidine-fullerene carriers with quantum chemistry calculations

Clonidine has two aromatic rings in which halogens are attached to one ring in this study, both in drug state and in fullerene nanostructure, and by changing the type of halogen at the * HF / 6-31G level and in The gas phase was first optimized and then the NBO calculations were performed. The results obtained in N61, N63 and N5, N3 indicate the highest rhizanese energy and load transfer that, ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • The journal of physical chemistry. B

دوره 115 22  شماره 

صفحات  -

تاریخ انتشار 2011